The lithium iron phosphate battery (LiFePO4 battery) or LFP battery (lithium ferrophosphate), is a type of lithium-ion battery using lithium iron phosphate (LiFePO4) as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode.[1] The energy density of LiFePO4 is lower than that of lithium cobalt oxide (LiCoO2), and also has a lower operating voltage. The main drawback of LiFePO4 is its low electrical conductivity.[2]
History
LiFePO
4 is a natural mineral of the olivine family (triphylite). Arumugam Manthiram and John B. Goodenough first identified the polyanion class of cathode materials for lithium ion batteries. LiFePO
4 was then identified as a cathode material belonging to the polyanion class for use in batteries in 1996 by Padhi et al. Reversible extraction of lithium from LiFePO
4 and insertion of lithium into FePO
4 was demonstrated.
[3] Because of its low cost, non-toxicity, the natural abundance of iron, its excellent thermal stability, safety characteristics, electrochemical performance, and specific capacity (170 mA·h/g, or 610 C/g) it has gained considerable market acceptance.
- ↑ Why lithium iron phosphate batteries are suitable for industrial and commercial applications
- ↑ Lithium iron phosphate batteries | Lithium Ion Battery Manufacturer | BSLBATT
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