Lithium iron phosphate battery

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The lithium iron phosphate battery (LiFePO4 battery) or LFP battery (lithium ferrophosphate), is a type of lithium-ion battery using lithium iron phosphate (LiFePO4) as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode.[1] The energy density of LiFePO4 is lower than that of lithium cobalt oxide (LiCoO2), and also has a lower operating voltage. The main drawback of LiFePO4 is its low electrical conductivity.[2]

History

LiFePO4 is a natural mineral of the olivine family (triphylite). Arumugam Manthiram and John B. Goodenough first identified the polyanion class of cathode materials for lithium ion batteries. LiFePO4 was then identified as a cathode material belonging to the polyanion class for use in batteries in 1996 by Padhi et al. Reversible extraction of lithium from LiFePO4 and insertion of lithium into FePO4 was demonstrated.[3] Because of its low cost, non-toxicity, the natural abundance of iron, its excellent thermal stability, safety characteristics, electrochemical performance, and specific capacity (170 mA·h/g, or 610 C/g) it has gained considerable market acceptance.
  1. Why lithium iron phosphate batteries are suitable for industrial and commercial applications
  2. Lithium iron phosphate batteries | Lithium Ion Battery Manufacturer | BSLBATT
  3. Building safer Li-lon batteries | Extending Battery Life | Doing your part for the environment